![]() By 2009, only 26 manufacturers worldwide produced carbon tetrachloride, including three in the United States. production and export of CCl 4 dropped precipitously during this time. By 2009, the United States no longer regularly imported CCl 4 only 90 pounds (41 kilograms) were imported during 1996-2009. īoth the internationally ratified Montreal Protocol (which first went into effect in 1989) and the United States 1990 Clean Air Act Amendments were instrumental in reducing environmental concentrations of CCl 4 and other ozone-depleting chemicals. It is not permitted in products intended for home use however, chemicals containing CCl 4 can still be purchased online. In the United States, CCl 4 use is restricted to industrial and laboratory applications only. a) Na, F b) Be, O C) Al, S d) K, Se e) Li, N f) Mg, P g) Ca, H Give the correct chemical formula for each of the following binary compounds: nonmetal-nonmetal. Environmental Protection Agency cancelled CCl 4‘s use as a fumigant in 1986. Write the chemical formula(s) of the ionic compounds formed between each of the following pairs (metal and nonmetal) of elements. CCl 4 was also used as an antihelminthic, a grain fumigant, and a component in fire extinguishers.Ĭarbon tetrachloride’s toxicity was recognized in the early 1900s, and most of the uses were discontinued by the mid-1960s. It was found in household cleaning supplies and spot removers for carpets, clothing, and furniture. In the United States, CCl 4 was also an ingredient in many industrial fluids, and was an effective metal degreaser. It can also cause damage to eyes and it is harmful to animals and environments, it cause damage to the ozone layer as well.Historically, CCl 4 was mainly used to produce chlorofluorocarbons (CFCs), which are used as heat transfer agents in refrigerating equipment and as aerosol propellants. Carbon tetrachloride is suspected to be a human carcinogen. It can cause degeneration of liver and kidneys. Health effects / safety hazards: Carbon tetrachloride is toxic and poisoning by inhalation or ingestion. Carbon tetrachloride is also used as cleaning agent and refrigerant in low concentrations. This compound is often classified as a polyhalogenated organic compound since it consists of a carbon atom which is attached to more than one halide functional group. It is also a solvent for some reactions in laboratory scale, however, its application is reduced due to it is poisoning by inhalation. What is Carbon Tetrachloride Carbon tetrachloride, also known as tetrachloromethane, is an organic compound with the chemical formula CCl4. Uses: Carbon tetrachloride is used to produce a wide variety of chemical compounds such as oils, lacquers, rubbers, resins and coats. ![]() Consequently, carbon tetrachloride is a solvent that can only be used to dissolve non-polar or low polarity compounds, such as fats and oils, thus it is used in the cleaning agents manufacturing. These bonds have dipolar vectors that are cancelled, resulting in a polarity of zero. It is not soluble in water, but it is soluble in ethanol, methanol, benzene, ether and hexane.Ĭhemical properties: Carbon tetrachloride is a non-polar molecule because its symmetrical structure formed by 4 C-Cl bonds. Carbon tetrachloride melting and boiling points are -22.92 ✬ and 76, 7 ✬, respectively. Physical properties: Carbon tetrachloride is a colorless liquid with a sweet, ether-like odor, Its density is 1.5867 g mL-1. ![]() Using the reaction of sulfur monochloride with cabon disulfide. Through the Lummus oxychlorination process with natural gas and HCl in its gas form The reaction of pyrolysis of hexachloroethane. By the reaction of chlorination of methane, which also produces other chlorides as CHCl 3, CH 2Cl 2 and CH 3Cl
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Another option is to eliminate or reform the filibuster, but that is unlikely to happen since Senator Joe Manchin has made it clear he won't support it. Without that support, Democrats could pass the packages via budget reconciliation, but that would require a completely unified caucus.
![]() Archer is teaming with United Airlines for New York City and Chicago. Joby is partnering with Delta Airlines for likely airport shuttle service in New York City and Los Angeles. “It’s hard to make the unit economics work in other use cases. “It looks like these eVTOL have settled on airport transfer as the launch use case,” says Deahl. Many other cities also have these helicopter services, and electric aircraft could be a drop-in replacement. New York does have several heliports along the water that already support shuttles to and from its far-flung airports. (Joby has demonstrated its craft as being not much louder than a boisterous conversation on take-off, but that’s different from the popular perception of aircraft.) Building more heliports, or “vertiports,” as eVTOL boosters call them, for crosstown travel faces the challenge of crowded airspace, scarce real estate, high construction costs, and a surfeit of lawyers poised to file noise complaints. Related Take Charge of Your Legacy With an Estate Plan ![]() In cities today, it’s limited to a few helicopter ports. “ much further behind where the eVTOL are,” says Dyment. Infrastructure Barely ExistsĮven FAA-approved aircraft and pilots still need somewhere to fly from and to. Deahl says they need to get certified for this “powered lift” class of aircraft. (Dyment says that NEXA invests in about half the companies covered in this article but would not reveal which ones.) Meanwhile, today’s licensed helicopter or airplane pilots can’t just drop into an eVTOL. Michael Dyment, founder and managing partner at NEXA Capital Partners, expects autonomous tech to be ready in 2030, at best. Autonomy eliminates a salary, makes room for another customer, and solves the pilot shortage problem. Going pilot-free is the ultimate ambition for all these companies. ![]() Launching a company like Uber or Lyft required only putting mass-produced cars with plentiful, already-licensed drivers onto an existing transportation network, using a smartphone app.” The company says it will begin service by 2030. (Joby did that in 2017, and Archer did just in May.) Wisk Aero is planning to launch once its planes can fly autonomously. It’s promising service-ready craft by 2026 but is still building its first full-scale prototype. “We change one little thing, add one little bit of innovation, and get it certified.” Instead of tweaks to tried-and-true airplane and helicopter designs, air taxi companies are trying to push radically new technologies through the certification process.Įve Air Mobility has announced high-profile sales agreements for nearly 3,000 aircraft with operators, including United Airlines and helicopter and plane charter broker Blade. “The aircraft business tends to be very incremental,” says Geurkink. Related AI Saves Critical Time in Cancer Detection (Deahl says that Alton does not consult with any of the companies mentioned in this article, but it works with competitors he declined to name.) “Joby and Archer, they’re both very well positioned with good cash reserves,” he says. “There’s actually never been a civil aircraft certified under that category before,” says Deahl.ĭespite the added challenge, he thinks the most prominent players can pull it off by 2025. But last year, it switched to instead require certification as “powered-lift” vehicles to account for their vertical ascent and descent. The FAA had planned to certify eVTOLs as small airplanes under a regulation called Part 23. There are several more steps to commercial service, and the route has just changed. Joby’s latest certification wasn’t a go-ahead for final passenger service but only for flight testing the production prototype of its to-be-named aircraft. None of that’s true for electric air taxis struggling to reach economies of scale. ![]() Launching a company like Uber or Lyft required only putting mass-produced cars with plentiful, already-licensed drivers onto an existing transportation network, using a smartphone-based dispatch system that doesn’t require regulatory approval. “I think it’s going to be pretty limited to who’s flying these things, who can afford to fly these things.” “Certainly, for the first few years, perhaps decades, it’s gonna be an expensive service,” says Jonathan Geurkink, senior analyst for emerging tech at capital markets research firm PitchBook. The Access Database Engine is not intended: ODBC and OLEDB drivers are installed for application developers to use in developing their applications with connectivity to Office file formats. Connectivity to existing text files is also supported. The Access 365 Runtime includes the Access Database Engine which contains a set of components that facilitate the transfer of data between existing Microsoft Office files such as Microsoft Office Access (*.mdb and *.accdb) files and Microsoft Office Excel (*.xls, *.xlsx, and *.xlsb) files to other data sources such as Microsoft SQL Server. The Access 365 Runtime is like previous runtimes in that all design-related UI is either removed or disabled. In the following drop-down list, select the language you want, and then click the appropriate bit version.ĭepending on your browser, select Run (in Edge or Internet Explorer), Setup (in Chrome), or Save File (in Firefox). If you see the User Account Control prompt that says, Do you want to allow this app to make changes to your device? select Yes. The install begins. ![]() For more information, see Choose between the 64-bit or 32-bit version of Office. The Microsoft 365 Access Runtime files are available as a free download in either the 32-bit (x86) or 64-bit (圆4) versions in all supported languages.ĭecide which bit version you need. For more information, see Office installed with Click-to-Run and Windows Installer on same computer isn't supported. The Microsoft 365 Access Runtime is not compatible with Office products installed with Windows Installer. For more information, see Unable to use the Access ODBC, OLEDB or DAO interfaces outside Office Click-to-Run applications. It’s recommended to use Office LTSC 2021 Volume License in this scenario. The Access Database Engine is not exposed to applications outside of Office when using the Volume License version of Office 2019. Use the Office Deployment Tool, if you desire to distribute the Microsoft 365 Access Runtime as part of deploying Office in your organization. For instance, if the machine has Office 2021 installed, Access 2021 Runtime will be installed. Ctrl+click each of these folders if present, and Move to Trash.When installing the Access 365 Runtime on a machine that has another Click-to-Run version of Office installed, the Access Runtime installed will match that of the existing Office installation. Click the back arrow to go back to the Library folder and open Group Containers.Note that some of these folders may not be present. Open the Containers folder and ctrl+click each of these folders and Move to Trash. In the window that opens, enter ~/Library and then click Go.Move the applications to the Recycle Bin by selecting them, pressing Command and clicking on one of the programs, then selecting Move to trash.This requires the following steps: MacOS: If you need to uninstall the application, but will need to re-install the application again, it is important to ensure that you remove all remnants of the applications and licenses associated with the applications. ![]() Uninstalling and re-installing Microsoft 365 This will ensure you get the full version of Microsoft 365 in accordance with the University's licence. Choose the apps you want from the list of search results.Īfter downloading the app, use your student email and password to sign in to the app. Go to the appropriate app store for your device and search for Microsoft 365. You can either install Microsoft Office (includes: Word, Excel, PowerPoint, as well as a document viewer) or each of the listed programs as separate apps.
![]() ![]() You can use homemade or store-bought mayonnaise depending on your preference. The mayo must be of good quality and have a creamy texture. Mayonnaise is the base of boom boom sauce, and it adds a creamy texture and richness to the sauce. Ingredients for making boom boom sauce 1. The combination of all the ingredients creates a uniquely delicious taste that distinguishes the Boom Boom Sauce from the rest. Make sure to gather all the ingredients before starting the cooking procedure. So, here are the essential ingredients needed to make the Boom Boom Sauce. It is a versatile ingredient used in numerous savory dishes and adds a good aroma to the sauce. Black Pepper: Black Pepper adds a sharp and pungent kick to the Boom Boom Sauce. It enhances the overall flavor of the sauce and balances all the ingredients perfectly.ġ0. Salt: Salt is a common ingredient used in almost every cooking recipe. It adds a mild onion-like taste, enhancing the spicy and tangy flavors of the sauce.ĩ. Onion Powder: Onion Powder is a perfect balance of sweet and savory flavor in the sauce. ![]() It brings out the aroma that you need in the sauce, making it more appetizing.Ĩ. Garlic Powder: Garlic powder pairs well with other ingredients and enhances the flavor of the sauce. This ingredient elevates the taste of the sauce, making it more gourmet and complex.ħ. Smoked Paprika: Smoked paprika adds a smoky flavor to the sauce, making it more flavorful. It is a classic condiment that adds a savory taste to meat and seafood dishes.Ħ. Worcestershire Sauce: Worcestershire sauce adds umami flavor to the sauce. It also brings a mild aroma to the sauce.ĥ. Honey: Honey helps to balance the spicy flavor of the sauce with its natural sweetness. It is one of the essential ingredients that create the unique taste and texture of the Boom Boom Sauce.Ĥ. Sriracha: Sriracha is a type of hot sauce made from chili peppers, vinegar, garlic, and sugar. It is a popular ingredient used in countless Asian recipes and adds bold flavors.ģ. Chili Garlic Sauce: Chili Garlic Sauce brings out the heat and spice in the sauce. It is essential to get the creamy texture and the tangy flavor of the sauce.Ģ. Mayonnaise: Mayonnaise is the base of the Boom Boom Sauce. Thank You for Enjoying the Flavorful Journey with Us!Īre you excited to make the famous Boom Boom Sauce? Before jumping into the cooking procedure, let us first discuss the list of ingredients you need to prepare for making the sauce.ġ.Use our tips and tricks to make your homemade boom boom sauce and enjoy it with your favorite dishes. With the right ingredients and proper whisking, you can have your flavorful and unique boom boom sauce. Making boom boom sauce is easy and fun, and the resulting taste is worth the effort. Experiment with different dishes to find the best pairing for your boom boom sauce. It’s also great as a dipping sauce for fries or as a salad dressing. You can also adjust the sweetness or spiciness of the sauce by adding more or less of certain ingredients.īoom boom sauce is perfect for serving with chicken, fish, seafood, or vegetables. ![]() Moreover, whisk the ingredients thoroughly to get a homogenous texture. When making boom boom sauce, it’s essential to use fresh ingredients to get the best taste. Ensure that you tightly close the lid to prevent any air from getting in, which can cause spoilage. Homemade boom boom sauce is also fresher and tastier than store-bought alternatives.īoom boom sauce can be stored in the refrigerator in an airtight container for up to two weeks. Additionally, making the sauce at home allows you to adjust the ingredients to suit your preferences. Making your boom boom sauce at home is cheaper than buying it from the store. Also, mayonnaise, soy sauce, and vinegar are common ingredients that you can find in any grocery store.Ħ. Check the Asian food section for chili sauce and sweet chili sauce. You can easily find the ingredients for making boom boom sauce at your local grocery store. This will help to allow the flavors to blend and harmonize, giving the sauce a unique taste. It’s important to refrigerate the boom boom sauce for at least 30 minutes or so before serving. ![]() ![]() Automatically invest spare change into the existing ETF portfolio.Some of the account’s primary features include: Later allows Acorns users to transfer payments into the IRA accounts from their taxes (transfers are treated as pre-tax income) and are only taxed as income when they retire - meaning users don’t have to be concerned about any taxable capital gains.Īcorns’ Banking product is a checking account with a debit card associated to it. The portfolio is selected based on the user’s age and proximity to retirement. With Later, Acorns sets aside a selected portion every month (starting as little as $5) and invests the money into the company’s Individual Retirement Accounts (IRA). ![]() Acorns can allocate a portion of the user’s balance towards Bitcoin as well. The firm will begin investing for an individual when their pool of change totals $5.Īdditionally, users have the option to only invest into companies with a focus on (environmental) sustainability (the company has also planted over 700,000 oaktrees in partnership with One Tree Planted). Acorns, depending on the user’s appetite for risk (conservative to aggressive), then invests the money into a mix of Exchange Traded Funds (ETFs). Users can create an investment portfolio within a few clicks. If, for instance, they buy a coffee for $3.50, Acorns automatically suggest the amount they could set aside (in this case $0.50) for their portfolio. Acorns links directly to the user’s credit card or bank account. Its Invest product is a micro-investing account that allows users to invest their spare change. (NASDAQ: TMUS) is America’s supercharged Un-carrier, delivering an advanced 4G LTE and transformative nationwide 5G network that will offer reliable connectivity for all. Latham & Watkins LLP served as lead legal counsel and advisor with Bernstein Shur also serving as legal counsel for Ka’ena Corporation. LionTree LLC served as lead financial advisor with BofA Securities and TAP Securities LLC also serving as financial advisors to Ka’ena Corporation. The transaction is expected to be slightly accretive to both Core Adjusted EBITDA and Free Cash Flow as T-Mobile captures the full long-term economic value of the Ka’ena business, including by securing financial benefits beyond the end of the current wholesale exclusivity period.Ĭleary Gottlieb Steen & Hamilton LLP served as legal advisor to T-Mobile. T-Mobile does not currently expect the transaction to have any impact on the company’s 2023 guidance or its ongoing stock repurchase program. The transaction is subject to the satisfaction of closing conditions, and is expected to close later this year. It is also subject to working capital adjustments and other contractual reserves. The actual price to be paid by T-Mobile will be based upon Ka’ena’s performance during certain periods before and after the closing. T-Mobile will pay up to a maximum of $1.35 billion in a combination of 39% cash and 61% stock to acquire Ka’ena. Owner Ryan Reynolds will continue on in his creative role on behalf of Mint. I am so proud of the entire Mint team and so excited for what’s to come,” said Ryan Reynolds.įollowing the deal’s close, Mint's founders David Glickman and Rizwan Kassim will remain onboard at T-Mobile to manage the brands, which will generally operate as a separate business unit. We are so happy T-Mobile beat out an aggressive last-minute bid from my mom Tammy Reynolds as we believe the excellence of their 5G network will provide a better strategic fit than my mom’s slightly-above-average mahjong skills. “Mint Mobile is the best deal in wireless and today’s news only enhances our ability to deliver for our customers. “This transaction validates our meteoric success and will unite two proven industry innovators committed to doing things differently in the wireless industry.” “Our brands have thrived on the T-Mobile network, and we are thrilled that this agreement will take them even further, bringing the many benefits of 5G to even more Americans,” said David Glickman, founder and CEO of Mint, Ultra and Plum. We think customers are really going to win with a more competitive and expansive Mint and Ultra.” “Over the long-term, we’ll also benefit from applying the marketing formula Mint has become famous for across more parts of T-Mobile. “Mint has built an incredibly successful digital direct-to-consumer business that continues to deliver for customers on the Un-carrier’s leading 5G network and now we are excited to use our scale and owners' economics to help supercharge it - and Ultra Mobile - into the future,” said Mike Sievert, CEO of T-Mobile. The Mint and Ultra brands are complementary to the company’s current prepaid service offerings Metro by T-Mobile, T-Mobile branded prepaid and Connect by T-Mobile. The Un-carrier will also be able to leverage Mint’s industry-leading digital D2C marketing expertise as part of its broader portfolio to reach new customer segments and geographies. T-Mobile is acquiring the brands' sales, marketing, digital, and service operations, and plans to use its supplier relationships and distribution scale to help the brands to grow and offer competitive pricing and greater device inventory to more U.S. With this deal, the brands’ exclusive use of the Un-carrier’s largest, fastest and most reliable 5G network will continue. Ultra Mobile, a unique wireless service offering international calling options to communities across the country and wholesaler Plum. BELLEVUE, Wash.-( BUSINESS WIRE)-T-Mobile US (NASDAQ: TMUS) today announced that it has entered into a definitive agreement to acquire Ka’ena Corporation and its subsidiaries and brands: Mint Mobile, a successful direct-to-consumer (D2C) prepaid wireless brand in the U.S. ![]() Even if you already have a do-it-all archive tool that extracts RAR files, RAR to ZIP Converter's speed and ease of use make it a go-to solution for everyday jobs. But RAR to ZIP Converter proves it can handle the process easily. Moreover, Aspose ZIP supports the widest range of compression algorithms, including ZIP, 7-Zip, TAR and CPIO. Since RAR to ZIP Converter is likely to be used for quick jobs instead of major archiving duty, it's likely to be fast enough at any setting.Ī surprising number of similar tools omit the password option, which can add new and special layers of frustration to your day. Aspose ZIP supports conversion from multiple archive formats such as RAR, ZIP, 7ZIP, TAR and CPIO archives in an easy way into the target format, making it the most comprehensive archiving application available. There's no Help file, but RAR to ZIP Converter is easy to figure out: Browse to the RAR archive file you want to extract, name the ZIP file, select compression, add passwords (if desired), and click "Save As." No- or low-compression processing is fastest, but even high compression jobs are fast. A progress bar rounds out the control suite. Compression level ranges from No Compression to The Best Compression, which is the slowest. It also works with tar.gz, 7zip, iso, and a number of other formats. It can be set as the default application to use with a zip file, if required. Fields for RAR File and ZIP File each have an optional password field. rar file extractor, this application works with a range of compression file formats, including. Download your converted ZIP file immediately. Step 3 - Download your converted ZIP file. When you're busy and have all kinds of windows open, RAR to ZIP Converter's super-basic user interface is a welcome sight. Select RAR file from your computer using the browse function. It offers different compression levels and password protection. RAR to ZIP Converter is compact, free, and easy to use. It converts RAR archive files to ZIP files, which more users have the tools to open. However, the app also offers the possibility of segmenting the folders or elements that you want to extract from each set.If you need to access RAR files, but don't have WinRAR or a compatible tool, try RAR to ZIP Converter. But it is not an open source archive file. Free of charge, this program provides all the essential tools to pack multiple files in a matter of seconds. RAR RAR is an archive file format that can compress data files similar to ZIP. In this sense, the utility has a password encryption system that will protect your information from access by unauthorized third parties.ĭownloading BreeZip: RAR & ZIP Extractor for Windows will allow you to compress or decompress files at the click of a button. On the other hand, the tool allows you to compress files securely. In any case, the compression speed will depend on the power of your computer and the size of the files involved in the process.Īnother strong point of BreeZip: RAR & ZIP Extractor is that the program is fully compatible with multiple compression formats such as ZIP, RAR, 7-Zip, TAR or Gzip. In BreeZip: RAR & ZIP Extractor you simply have to select the files to be compressed to execute a process that will only take a few seconds. Its simple interface and ease of use will allow you to reduce the size of the files you share or store without having to resort to other paid tools. ![]() BreeZip: RAR & ZIP Extractor is a program that will allow you to compress different files from your PC equipped with Windows. ![]() ![]() Jackson Mountain Homes - Gatlinburg is home to Jackson Mountain Homes, the premier source for vacation rental properties in Gatlinburg and the surrounding Great Smoky Mountains area.įireside Chalet and Cabin Rentals - Fireside Chalets and Log Cabin Rentals of Pigeon Forge invites you to our uniquely designed chalets and log cabins, fully furnished and available for your Pigeon Forge or Smoky Mountain Vacation. Cabins with all the amenities to offer you a one-of-a-kind getaway to satisfy your desire for relaxation, comfort and excitement. 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ACSM does not typically own the copyright on these projects.ĪCSM's books are typically published by a publishing partner. When you open it, it should launch Adobe Digital. This will download an ACSM file to your computer. If the book you want is unavailable, click Place a Hold to be notified when you can borrow it. ![]() An example includes Coaching Psychology Manual. On the left side under Format, select eBook. “Published in Cooperation With” projects in which ACSM reviews and endorses the content.Official ACSM books, such as ACSM’s Guidelines for Exercise Testing and Prescription, ACSM’s Introduction to Exercise Science, and ACSM’s Complete Guide to Fitness & Health. ACSM owns the copyright on these projects.Projects generally are divided into two categories: Use it to download and purchase digital content, which can be read both online and offline. Download this free eReader to experience your books in the most optimum format across PC, MAC, tablets or mobile devices. Projects should relate to the ACSM mission statement: "The American College of Sports Medicine promotes and integrates scientific research, education, and practical applications of sports medicine and exercise science to maintain and enhance physical performance, fitness, health, and quality of life." Most major publishers use Adobe Digital Editions (ADE) to proof-read their books. Note: If you're using the Firefox browser, you'll also need to change the ACSM file association there (to make sure Firefox opens ACSM files with the correct program). The College publishes content for educational, professional, certification and consumer audiences. If you're having trouble opening ebooks in ADE, try the steps below to make sure that your computer opens ACSM files (which are used to download ebooks) in Adobe Digital Editions. acsm file, which should automatically open in Adobe Digital Editions. ![]() ACSM welcomes questions and publishing proposals from individuals and commercial publishers. If you have a new device/reader, follow the setup instructions included with. |
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